Syntheses, characterizations and electrochromic applications of polymers derived from carbazole containing thiophene rings in side chain with electrochemical and FeCl3 methods
Identifieur interne : 000423 ( Main/Repository ); précédent : 000422; suivant : 000424Syntheses, characterizations and electrochromic applications of polymers derived from carbazole containing thiophene rings in side chain with electrochemical and FeCl3 methods
Auteurs : RBID : Pascal:13-0143261Descripteurs français
- Pascal (Inist)
- Dispositif électrochromique, Effet électrooptique, Electrochromisme, Chaîne latérale, Méthode électrochimique, Revêtement, Addition étain, Polymérisation électrolytique, Commutation, Coefficient absorption, Facteur transmission, Résonance magnétique nucléaire, Spectre photoélectron RX, Stabilité thermique, Sonde 4 pointes, Electromètre, Propriété surface, Microscopie électronique balayage, Polymère, Dérivé du carbazole, Dérivé du thiophène, Chlorure de fer, Copolymère, Thiophène, Matériau revêtu, Oxyde d'indium, Verre, Etat solide, Matériau dopé, 8560P, 8105L, 8105K, 0779, FeCl3, ITO.
- Wicri :
English descriptors
- KwdEn :
- Absorption coefficient, Carbazole derivatives, Coated material, Coatings, Copolymer, Doped materials, Electrochemical method, Electrochemical polymerization, Electrochromic device, Electrochromism, Electrometer, Electrooptical effect, Four point probe, Glass, Indium oxide, Iron chloride, Nuclear magnetic resonance, Polymer, Scanning electron microscopy, Side chain, Solid state, Surface properties, Switching, Thermal stability, Thiophene, Thiophene derivatives, Tin addition, Transmittance, X-ray photoelectron spectra.
Abstract
1,8-Bis(3,6-di(thiophen-3-yl)-9H-carbazol-9-yl)octane (BDTCO) was synthesized via Ullmann and Suzuki couplings. Additionally, its homopolymer and copolymers with 3,4-ethylenedioxythiophene (EDOT), pyrrole (Py) and thiophene (Th) were synthesized and coated onto an ITO-glass surface via electrochemical oxidative polymerization. The spectroelectrochemical and electrochromic properties of the polymers were also investigated. The switching ability of these polymers was measured as the percent transmittance (T%) at their point of maximum contrast. Moreover, the polymer of BDTCO (P-BDTCO) was successfully synthesized through FeCl3 oxidative polymerization. The compounds were characterized by FT-IR, NMR and X-ray Photoelectron Spectroscopy (XPS), and their thermal stabilities were determined via TG measurements. The solid state conductivities of the polymeric films coated onto the ITO-glass surface were measured via the four point probe technique using an electrometer. In addition, the surface morphological properties were investigated by Scanning Electron Microscopy (SEM) for different magnifications.
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<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en" level="a">Syntheses, characterizations and electrochromic applications of polymers derived from carbazole containing thiophene rings in side chain with electrochemical and FeCl<sub>3</sub> methods</title><author><name sortKey="Aydin, Aysel" uniqKey="Aydin A">Aysel Aydin</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Cnakkale Onsekiz Mart University, Faculty of Sciences and Arts, Department of Chemistry, Polymer Analysis Laboratory</s1><s2>17020 Çanakkale</s2><s3>TUR</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ></inist:fA14><country>Turquie</country><wicri:noRegion>17020 Çanakkale</wicri:noRegion></affiliation></author><author><name sortKey="Kaya, Ismet" uniqKey="Kaya I">Ismet Kaya</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Cnakkale Onsekiz Mart University, Faculty of Sciences and Arts, Department of Chemistry, Polymer Analysis Laboratory</s1><s2>17020 Çanakkale</s2><s3>TUR</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ></inist:fA14><country>Turquie</country><wicri:noRegion>17020 Çanakkale</wicri:noRegion></affiliation></author></titleStmt><publicationStmt><idno type="inist">13-0143261</idno><date when="2013">2013</date><idno type="stanalyst">PASCAL 13-0143261 INIST</idno><idno type="RBID">Pascal:13-0143261</idno><idno type="wicri:Area/Main/Corpus">000F85</idno><idno type="wicri:Area/Main/Repository">000423</idno></publicationStmt><seriesStmt><idno type="ISSN">1566-1199</idno><title level="j" type="abbreviated">Org. electron. : (Print)</title><title level="j" type="main">Organic electronics : (Print)</title></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Absorption coefficient</term><term>Carbazole derivatives</term><term>Coated material</term><term>Coatings</term><term>Copolymer</term><term>Doped materials</term><term>Electrochemical method</term><term>Electrochemical polymerization</term><term>Electrochromic device</term><term>Electrochromism</term><term>Electrometer</term><term>Electrooptical effect</term><term>Four point probe</term><term>Glass</term><term>Indium oxide</term><term>Iron chloride</term><term>Nuclear magnetic resonance</term><term>Polymer</term><term>Scanning electron microscopy</term><term>Side chain</term><term>Solid state</term><term>Surface properties</term><term>Switching</term><term>Thermal stability</term><term>Thiophene</term><term>Thiophene derivatives</term><term>Tin addition</term><term>Transmittance</term><term>X-ray photoelectron spectra</term></keywords><keywords scheme="Pascal" xml:lang="fr"><term>Dispositif électrochromique</term><term>Effet électrooptique</term><term>Electrochromisme</term><term>Chaîne latérale</term><term>Méthode électrochimique</term><term>Revêtement</term><term>Addition étain</term><term>Polymérisation électrolytique</term><term>Commutation</term><term>Coefficient absorption</term><term>Facteur transmission</term><term>Résonance magnétique nucléaire</term><term>Spectre photoélectron RX</term><term>Stabilité thermique</term><term>Sonde 4 pointes</term><term>Electromètre</term><term>Propriété surface</term><term>Microscopie électronique balayage</term><term>Polymère</term><term>Dérivé du carbazole</term><term>Dérivé du thiophène</term><term>Chlorure de fer</term><term>Copolymère</term><term>Thiophène</term><term>Matériau revêtu</term><term>Oxyde d'indium</term><term>Verre</term><term>Etat solide</term><term>Matériau dopé</term><term>8560P</term><term>8105L</term><term>8105K</term><term>0779</term><term>FeCl3</term><term>ITO</term></keywords><keywords scheme="Wicri" type="concept" xml:lang="fr"><term>Polymère</term><term>Verre</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">1,8-Bis(3,6-di(thiophen-3-yl)-9H-carbazol-9-yl)octane (BDTCO) was synthesized via Ullmann and Suzuki couplings. Additionally, its homopolymer and copolymers with 3,4-ethylenedioxythiophene (EDOT), pyrrole (Py) and thiophene (Th) were synthesized and coated onto an ITO-glass surface via electrochemical oxidative polymerization. The spectroelectrochemical and electrochromic properties of the polymers were also investigated. The switching ability of these polymers was measured as the percent transmittance (T%) at their point of maximum contrast. Moreover, the polymer of BDTCO (P-BDTCO) was successfully synthesized through FeCl<sub>3</sub> oxidative polymerization. The compounds were characterized by FT-IR, NMR and X-ray Photoelectron Spectroscopy (XPS), and their thermal stabilities were determined via TG measurements. The solid state conductivities of the polymeric films coated onto the ITO-glass surface were measured via the four point probe technique using an electrometer. In addition, the surface morphological properties were investigated by Scanning Electron Microscopy (SEM) for different magnifications.</div></front></TEI><inist><standard h6="B"><pA><fA01 i1="01" i2="1"><s0>1566-1199</s0></fA01><fA03 i2="1"><s0>Org. electron. : (Print)</s0></fA03><fA05><s2>14</s2></fA05><fA06><s2>3</s2></fA06><fA08 i1="01" i2="1" l="ENG"><s1>Syntheses, characterizations and electrochromic applications of polymers derived from carbazole containing thiophene rings in side chain with electrochemical and FeCl<sub>3</sub> methods</s1></fA08><fA11 i1="01" i2="1"><s1>AYDIN (Aysel)</s1></fA11><fA11 i1="02" i2="1"><s1>KAYA (Ismet)</s1></fA11><fA14 i1="01"><s1>Cnakkale Onsekiz Mart University, Faculty of Sciences and Arts, Department of Chemistry, Polymer Analysis Laboratory</s1><s2>17020 Çanakkale</s2><s3>TUR</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ></fA14><fA20><s1>730-743</s1></fA20><fA21><s1>2013</s1></fA21><fA23 i1="01"><s0>ENG</s0></fA23><fA43 i1="01"><s1>INIST</s1><s2>27255</s2><s5>354000500610690050</s5></fA43><fA44><s0>0000</s0><s1>© 2013 INIST-CNRS. All rights reserved.</s1></fA44><fA45><s0>39 ref.</s0></fA45><fA47 i1="01" i2="1"><s0>13-0143261</s0></fA47><fA60><s1>P</s1></fA60><fA61><s0>A</s0></fA61><fA64 i1="01" i2="1"><s0>Organic electronics : (Print)</s0></fA64><fA66 i1="01"><s0>NLD</s0></fA66><fC01 i1="01" l="ENG"><s0>1,8-Bis(3,6-di(thiophen-3-yl)-9H-carbazol-9-yl)octane (BDTCO) was synthesized via Ullmann and Suzuki couplings. Additionally, its homopolymer and copolymers with 3,4-ethylenedioxythiophene (EDOT), pyrrole (Py) and thiophene (Th) were synthesized and coated onto an ITO-glass surface via electrochemical oxidative polymerization. The spectroelectrochemical and electrochromic properties of the polymers were also investigated. The switching ability of these polymers was measured as the percent transmittance (T%) at their point of maximum contrast. Moreover, the polymer of BDTCO (P-BDTCO) was successfully synthesized through FeCl<sub>3</sub> oxidative polymerization. The compounds were characterized by FT-IR, NMR and X-ray Photoelectron Spectroscopy (XPS), and their thermal stabilities were determined via TG measurements. The solid state conductivities of the polymeric films coated onto the ITO-glass surface were measured via the four point probe technique using an electrometer. 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l="FRE"><s0>FeCl3</s0><s4>INC</s4><s5>82</s5></fC03><fC03 i1="35" i2="X" l="FRE"><s0>ITO</s0><s4>INC</s4><s5>83</s5></fC03><fN21><s1>119</s1></fN21><fN44 i1="01"><s1>OTO</s1></fN44><fN82><s1>OTO</s1></fN82></pA></standard></inist></record>Pour manipuler ce document sous Unix (Dilib)
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